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Trace Total Mercury Analysis
Mercury Speciation of River Water
Mercury Speciation of Lake Water
Mercury Speciation of Soil
Mercury Speciation of Tissue
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Comparison of hydride generation and IC-ICP-MS for selenium speciation analysis (pdf)
Selenium Speciation in FGD Plant Effluents
Trace (ppt level) Total Selenium and Arsenic Analysis Method (pdf)
Selenium
is becoming a priority pollutant in many parts of North America
because of its high toxicity to aquatic wildlife. Many mining
operations face extensive regulation with respect to their selenium
discharges, which results from accidental mobilization during the
respective mining process.
In all environmental and industrial processes, individual selenium
species differ greatly in their behavior, so the determination of
these individual species and their relative distribution is of
critical importance. In lower concentrations, selenium is a
necessary nutrient for the existence of life; however, at
concentrations ten times the recommended dosage, selenium becomes a
carcinogen with direct health impacts.
Methods for Selenium Speciation Analysis: Applied Speciation employs
anion chromatography coupled with the detection power of our
ICP-DRC-MS for Selenium Speciation Analysis. The Dynamic Reaction
cell is used to eliminate the background signal from the plasma gas
components allowing us to achieve detection limits around 10 ppt (ng/L).
During Selenium Speciation Analysis, the species of interest are
usually selenite (Se(IV)) and selenate (Se(VI)). Elemental selenium
is usually mobilized by cyanide and therefore, the main species
after mobilization is selenocyanate (SeCN) and selenate. Since
selenocyanate can be present in many mining wastewaters, we have a
method that includes SeCN in the separation scheme. Just like
arsenic speciation, depending on the matrix, different analytical
separation modes can be utilized for selenium speciation analysis to
improve detection and/or eliminate certain interferences/problems.
If you have any questions regarding services or would like a
quotation, please feel free to email us at
info@appliedspeciation.com or call
(425) 483-3300.
Feel free to visit our website on a regular basis as we will be
providing scientific discussions and useful links to save you time
and money.
- Key information on Selenium from WebElements
- EPA Air Toxics Website provides information on selenium and selenium compounds
- ATSDR - Toxicological Profile on Selenium
Applied Speciation and Consulting 2009